[chore] Update Instrumentation example with python env var #1330
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Related to #924
Updates the README's Instrumentation object to explicitly set python's OTEL_EXPORTER_OTLP_ENDPOINT value to 4318.
If we want we can also update the python injection to update any existing OTEL_EXPORTER_OTLP_ENDPOINT value to be
4318
so that this distinction isn't necessary, but I think that change needs some scrutiny to make sure users can still configure anything they want with confidence that we aren't messing with it.