Content structure tweaks to Doc Blocks guide

[kylegach]

What I did

Before

After

Checklist

• Make sure your changes are tested (stories and/or unit, integration, or end-to-end tests)
• Make sure to add/update documentation regarding your changes
• If you are deprecating/removing a feature, make sure to update
  MIGRATION.MD

Maintainers

• If this PR should be tested against many or all sandboxes,
  make sure to add the ci:merged or ci:daily GH label to it.
• Make sure this PR contains one of the labels below.

["cleanup", "BREAKING CHANGE", "feature request", "bug", "documentation", "maintenance", "dependencies", "other"]

[domyen]

lgtm! Should I worry about the UI Test?

[kylegach]

Should I worry about the UI Test?

No, that's unrelated.