diff --git a/pyscses/calculation.py b/pyscses/calculation.py index d8a9eb2..43589ce 100644 --- a/pyscses/calculation.py +++ b/pyscses/calculation.py @@ -287,7 +287,7 @@ def form_subgrids(self, subgrids = {} for label in site_labels: name = '{}'.format( label ) - subgrids[name] = self.grid.subgrid( label ) + subgrids[name] = self.grid.subgrid(label) subgrids[name].delta_x[0] = subgrids[name].delta_x[1] subgrids[name].delta_x[-1] = subgrids[name].delta_x[1] subgrids[name].volumes[0] = subgrids[name].volumes[1] @@ -495,9 +495,8 @@ def mole_fractions(self) -> None: """ mole_fractions = {} for label in self.site_labels: - name = '{}'.format(label) - subgrid_set_of_sites = self.subgrids[name].set_of_sites # actually a list - mole_fractions[name] = SetOfSites(subgrid_set_of_sites).calculate_probabilities(self.grid, self.phi, self.temp) + subset_of_sites = self.subgrids[label].set_of_sites + mole_fractions[label] = subset_of_sites.calculate_probabilities(self.grid, self.phi, self.temp) self.mf = mole_fractions def diff_central(x: np.ndarray, diff --git a/pyscses/grid.py b/pyscses/grid.py index 850142d..a353372 100644 --- a/pyscses/grid.py +++ b/pyscses/grid.py @@ -175,7 +175,7 @@ def __init__( self, x_coordinates, b, c, limits, limits_for_laplacian, set_of_si self.b = b self.c = c self.set_of_sites = set_of_sites - print(f"In Grid: type(set_of_sites) is {type(set_of_sites)}") + # print(f"In Grid: type(set_of_sites) is {type(set_of_sites)}") self.defect_species = [] for site in set_of_sites: i = index_of_grid_at_x( self.x, site.x ) @@ -255,7 +255,7 @@ def interpolated_energies( self ): energies.append( interpolated_energies ) return energies - def subgrid( self, subset_species ): + def subgrid(self, subset_species): """ Creates a subgrid for each species. diff --git a/pyscses/set_of_sites.py b/pyscses/set_of_sites.py index 09bb100..0614290 100644 --- a/pyscses/set_of_sites.py +++ b/pyscses/set_of_sites.py @@ -1,74 +1,95 @@ -import numpy as np -from pyscses.grid import Grid +from __future__ import annotations from scipy.interpolate import griddata # type: ignore +import numpy as np import math from pyscses.set_up_calculation import site_from_input_file, load_site_data from pyscses.grid import index_of_grid_at_x, phi_at_x, energy_at_x -from pyscses.site import Site from pyscses.constants import boltzmann_eV +from pyscses.defect_species import DefectSpecies from bisect import bisect_left +from typing import List, Iterator, Tuple, Optional +from typing import TYPE_CHECKING +if TYPE_CHECKING: + from pyscses.site import Site + from pyscses.grid import Grid class SetOfSites: - """The SetOfSites object groups together all of the Site objects into one object and contains functions for the calculations that provide properties of all of the sites together rather than individually. """ - def __init__(self, sites): + """The SetOfSites object groups together all of the Site objects into one object and + contains functions for the calculations that provide properties of all of the sites + together rather than individually. + + Attributes: + sites (list(Site)): List of Site objects. + + """ + def __init__(self, + sites: List[Site]) -> None: + """Initialise a SetOfSites object.""" self.sites = sites - def __add__( self, other ): - """ Allows the concatenation of multiple SetOfSites objects""" - if type( other ) is not SetOfSites: + def __add__(self, + other: SetOfSites) -> SetOfSites: + """Allows the concatenation of multiple SetOfSites objects""" + if type(other) is not SetOfSites: raise TypeError - return SetOfSites( self.sites + other.sites ) + return SetOfSites(self.sites + other.sites) - def __getitem__( self, index ): - """ Returns the site corresponding to a given index """ - return self.sites[ index ] + def __getitem__(self, + index: int) -> Site: + """Returns the site corresponding to a given index """ + return self.sites[index] - def __iter__(self): - """ - Iterator over self.sites - """ + def __iter__(self) -> Iterator[Site]: + """Iterator over self.sites""" return iter(self.sites) - def subset( self, label ): - """Returns a list of all the sites which contain a particular defect """ - return [ s for s in self.sites if s.label == label ] + def subset(self, + label: str) -> SetOfSites: + """Returns a subset of all the sites which contain a particular defect """ + return SetOfSites(sites=[s for s in self.sites if s.label == label]) - def get_coords( self, label ): + def get_coords(self, + label: str) -> List[float]: """ Returns a list of the x coordinates for all the sites wich contain a particular defect - Args: - label (str): Label identifying the required defect species. + Args: + label (str): Label identifying the required defect species. - Returns: - list: List of sites for a specific defect species. + Returns: + list(float): List of site coordinates for a specific defect species. - """ - return [ s.x for s in self.sites if s.label == label ] + """ + return [s.x for s in self.sites if s.label == label] - def calculate_energies_on_grid( self, grid, phi ): + def calculate_energies_on_grid(self, + grid: Grid, + phi: np.ndarray) -> np.ndarray: """ Returns an array of energies at their points on a one-dimensional grid. Args: - grid (object): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. + grid (Grid): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. phi (array): electrostatic potential on a one-dimensional grid. Returns: array: energies at their grid points """ - energies_on_grid = np.zeros_like( grid ) + energies_on_grid = np.zeros_like(grid.x) for site in self.sites: - energies_on_grid[index_of_grid_at_x( grid.x, site.x )] =+ energy_at_x( site.defect_energies, grid.x, site.x ) + energies_on_grid[index_of_grid_at_x(grid.x, site.x)] =+ energy_at_x(site.defect_energies, grid.x, site.x) return energies_on_grid - def calculate_probabilities( self, grid, phi, temp ): + def calculate_probabilities(self, + grid: Grid, + phi: np.ndarray, + temp: float) -> np.ndarray: """ Calculates the probability of a site being occupied by its corresponding defect. Args: - grid (object): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. + grid (Grid): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. phi (array): electrostatic potential on a one-dimensional grid. temp (float): Absolute temperature. @@ -88,12 +109,15 @@ def calculate_probabilities( self, grid, phi, temp ): probability[i] = np.mean(prob) return probability - def calculate_defect_density( self, grid, phi, temp ): + def calculate_defect_density(self, + grid: Grid, + phi: np.ndarray, + temp: float) -> np.ndarray: """ Calculates the defect density at each site. Args: - grid (object): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. + grid (Grid): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. phi (array): electrostatic potential on a one-dimensional grid. temp (float): Absolute temperature. @@ -107,13 +131,17 @@ def calculate_defect_density( self, grid, phi, temp ): defect_density[ i ] += np.asarray( site.probabilities( phi_at_x( phi, grid.x, site.x ), temp ) ) / grid.volumes[ i ] return defect_density - def subgrid_calculate_defect_density( self, sub_grid, full_grid, phi, temp ): + def subgrid_calculate_defect_density(self, + sub_grid: Grid, + full_grid: Grid, + phi: np.ndarray, + temp: float) -> np.ndarray: """ Calculates the defect density at each site for a given subset of sites. Args: - subgrid (object): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. For a given subset of sites. - full_grid (object): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. For all sites. + subgrid (Grid): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. For a given subset of sites. + full_grid (Grid): Grid object - contains properties of the grid including the x coordinates and the volumes. Used to access the x coordinates. For all sites. phi (array): electrostatic potential on a one-dimensional grid. temp (float): Absolute temperature. @@ -127,59 +155,76 @@ def subgrid_calculate_defect_density( self, sub_grid, full_grid, phi, temp ): defect_density[ i ] += np.asarray( site.probabilities( phi_at_x( phi, full_grid.x, site.x ), temp ) ) / sub_grid.volumes[ i ] return defect_density - def form_continuum_sites( all_sites, x_min, x_max, n_points, b, c, defect_species, limits_for_laplacian, site_labels, defect_labels ): - """ - Creates a SetOfSites object for sites interpolated onto a regular grid, this is equivalent to assuming a continuum approximation. - - Args: - all_sites (object): Orginal SetOfSites object from full data. - x_min (float): Minimum x coordinate value defining the calculation region. - x_max (float): Maximum x coordinate value defining the calculation region. - n_points (int): Number of points that the data should be interpolated on to. - b (float): b dimension for every grid point. - c (float): c dimension for every grid point. - defect_species (object): Class object containing information about the defect species present in the system. - limits for laplacian (list): distance between the endmost sites and the midpoint of the next site outside of the calculation region for the first and last sites respectively. - site_labels( list ): List of strings for the different site species. - defect_labels (list): List of strings for the different defect species. - - Returns: - :obj:`SetOfSites`: Sites interpolated onto a regular grid. - - """ - - grid = np.linspace( x_min, x_max, n_points ) - limits = [grid[1] - grid[0], grid[1] - grid[0]] - sites = [] - for label, d_label in zip(site_labels, defect_labels): - scaling = len( all_sites.subset( label ) ) / len( grid ) - continuum_grid = Grid(grid, b, c, limits, limits_for_laplacian, all_sites.subset(label)) - average_energies = np.array( [ site.average_local_energy( method = 'mean' )[0] for site in all_sites.subset( label ) ] ) - new_energies = griddata( ( [ site.x for site in all_sites.subset( label ) ] ), average_energies, grid, method = 'nearest' ) - for x, e in zip( grid, new_energies): - sites.append( Site( label, x, [ defect_species[ d_label ] ], [e], scaling = np.array( scaling ) ) ) - return SetOfSites( sites ), limits +# BEN: Does not appear to be called? +# def form_continuum_sites(all_sites, +# x_min, +# x_max, +# n_points, +# b, +# c, +# defect_species, +# limits_for_laplacian, +# site_labels, +# defect_labels): +# """ +# Creates a SetOfSites object for sites interpolated onto a regular grid, this is equivalent to assuming a continuum approximation. +# +# Args: +# all_sites (SetOfSites): Orginal SetOfSites object from full data. +# x_min (float): Minimum x coordinate value defining the calculation region. +# x_max (float): Maximum x coordinate value defining the calculation region. +# n_points (int): Number of points that the data should be interpolated on to. +# b (float): b dimension for every grid point. +# c (float): c dimension for every grid point. +# defect_species (object): Class object containing information about the defect species present in the system. +# limits for laplacian (list): distance between the endmost sites and the midpoint of the next site outside of the calculation region for the first and last sites respectively. +# site_labels( list ): List of strings for the different site species. +# defect_labels (list): List of strings for the different defect species. +# +# Returns: +# :obj:`SetOfSites`: Sites interpolated onto a regular grid. +# +# """ +# +# grid = np.linspace( x_min, x_max, n_points ) +# limits = [grid[1] - grid[0], grid[1] - grid[0]] +# sites = [] +# for label, d_label in zip(site_labels, defect_labels): +# scaling = len( all_sites.subset( label ) ) / len( grid ) +# continuum_grid = Grid(grid, b, c, limits, limits_for_laplacian, all_sites.subset(label)) +# average_energies = np.array( [ site.average_local_energy( method = 'mean' )[0] for site in all_sites.subset( label ) ] ) +# new_energies = griddata( ( [ site.x for site in all_sites.subset( label ) ] ), average_energies, grid, method = 'nearest' ) +# for x, e in zip( grid, new_energies): +# sites.append( Site( label, x, [ defect_species[ d_label ] ], [e], scaling = np.array( scaling ) ) ) +# return SetOfSites( sites ), limits @ classmethod - def set_of_sites_from_input_data( cls, input_data, limits, defect_species, site_charge, core, temperature, offset=0.0 ): + def set_of_sites_from_input_data(cls: object, + filename: str, + limits: Tuple[float, float], + defect_species: List[DefectSpecies], + site_charge: bool, + core: str, + temperature: float, + offset: float = 0.0) -> SetOfSites: """ Takes the data from the input file and creates a SetOfSites object for those sites. - The input data file is a .txt file where each line in the file corresponds to a site. The values in each line are formatted and separated into the corresponding properties before creating a Site object for each site. + The input data file is a .txt file where each line in the file corresponds to a site. The values in each line are formatted and separated into the corresponding properties before creating a Site object for each site. Args: - input_data (file): A .txt file where each line includes the information about a site. - limits (list): Minimum and maximum x coordinated defining the calculation region. - defect_species (object): Class object containing information about the defect species present in the system. - site_charge (bool): The site charge refers to the contribution to the overall charge of a site given by the original, non-defective species present at that site. True if the site charge contribution is to be included in the calculation, False if it is not to be included. - core (str): Core definition. 'single' = Single segregation energy used to define the core. 'multi-site' = Layered segregation energies used to define the core while the energies fall in the region of positive and negative kT. 'all' = All sites between a minimum and maximum x coordinate used in calculation. - temperature (float): Temperature that the calculation is being run at. - - Returns: - :obj:`SetOfSites`: `SetOfSites` object for the input data. - - """ - site_data = load_site_data( input_data, limits[0], limits[1], site_charge, offset ) - energies = [ line[4] for line in site_data ] + filename (str): Name of the input file to be parsed. + limits (list): Minimum and maximum x coordinated defining the calculation region. + defect_species (object): Class object containing information about the defect species present in the system. + site_charge (bool): The site charge refers to the contribution to the overall charge of a site given by the original, non-defective species present at that site. True if the site charge contribution is to be included in the calculation, False if it is not to be included. + core (str): Core definition. 'single' = Single segregation energy used to define the core. 'multi-site' = Layered segregation energies used to define the core while the energies fall in the region of positive and negative kT. 'all' = All sites between a minimum and maximum x coordinate used in calculation. + temperature (float): Temperature that the calculation is being run at. + + Returns: + :obj:`SetOfSites`: `SetOfSites` object for the input data. + + """ + site_data = load_site_data(filename, limits[0], limits[1], site_charge, offset) + energies = [line[4] for line in site_data] min_energy = min(energies) if core == 'single': for line in site_data: @@ -189,7 +234,7 @@ def set_of_sites_from_input_data( cls, input_data, limits, defect_species, site_ for line in site_data: if ( -boltzmann_eV * temperature) <= line[4] <= ( boltzmann_eV * temperature ): line[4] = 0.0 - return SetOfSites( [ site_from_input_file( line, defect_species, site_charge, core, temperature ) for line in site_data ] ) + return SetOfSites([site_from_input_file(line, defect_species, site_charge, core, temperature) for line in site_data]) @ classmethod def core_width_analysis( cls, input_data, limits, defect_species, site_charge, core, temperature ): diff --git a/tests/test_notebooks/test_1/test_notebook_1.ipynb b/tests/test_notebooks/test_1/test_notebook_1.ipynb index 897354e..828e492 100644 --- a/tests/test_notebooks/test_1/test_notebook_1.ipynb +++ b/tests/test_notebooks/test_1/test_notebook_1.ipynb @@ -122,5188 +122,17 @@ "name": "stdout", "output_type": "stream", "text": [ - 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"In Grid: type(set_of_sites) is \n", "Iteration: 2000 -> Convergence: 6.407008310764769e-05 / 1e-06\n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - 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"In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", "Iteration: 2500 -> Convergence: 2.641345352581461e-05 / 1e-06\n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - 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"In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - 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"In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", "Iteration: 5000 -> Convergence: 1.015070044794803e-06 / 1e-06\n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "Converged at iteration 5014 -> Convergence: 9.9928313960665e-07 / 1e-06\n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n", - "In Grid: type(set_of_sites) is \n" + "Converged at iteration 5014 -> Convergence: 9.9928313960665e-07 / 1e-06\n" ] } ], @@ -5414,7 +243,7 @@ "plt.plot(grid.x, c_o.phi)\n", "plt.xlabel( '$x$ $\\mathrm{coordinate}$' )\n", "plt.ylabel('$\\Phi$ $\\mathrm{( eV )}$')\n", - "plt.xlim( -5e-9, 5e-9)\n", + "plt.xlim(-5e-9, 5e-9)\n", "plt.ylim(min(c_o.phi))\n", "plt.savefig('generated_outputs/x_vs_potential.pdf')\n", "plt.show()\n",