diff --git a/sdk/monitor/Azure.Monitor.OpenTelemetry.AspNetCore/CHANGELOG.md b/sdk/monitor/Azure.Monitor.OpenTelemetry.AspNetCore/CHANGELOG.md
index a265b8879d510..5b95067073513 100644
--- a/sdk/monitor/Azure.Monitor.OpenTelemetry.AspNetCore/CHANGELOG.md
+++ b/sdk/monitor/Azure.Monitor.OpenTelemetry.AspNetCore/CHANGELOG.md
@@ -8,6 +8,15 @@
 
 ### Bugs Fixed
 
+* Fixed an issue where a `DuplicateKeyException` could be thrown if `EventId`
+  and `EventName` were present in both `LogRecord` (`LogRecord.EventId`,
+  `LogRecord.EventName`) and `LogRecord.Attributes`. The method now uses
+  `EventId` and `EventName` from `LogRecord.Attributes` when both are present.
+  If they are not in `LogRecord.Attributes`, it uses the values from
+  `LogRecord.EventId` or `LogRecord.EventName`, preventing the `LogRecord` from
+  being dropped.
+  ([#44748](https://github.com/Azure/azure-sdk-for-net/pull/44748))
+
 ### Other Changes
 
 * Enabled support for log collection from Azure SDKs via `Microsoft.Extensions.Logging`.
diff --git a/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/src/Internals/LogsHelper.cs b/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/src/Internals/LogsHelper.cs
index 2892fbec5edfd..c4dce94f2f3de 100644
--- a/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/src/Internals/LogsHelper.cs
+++ b/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/src/Internals/LogsHelper.cs
@@ -124,12 +124,12 @@ internal static List<TelemetryItem> OtelToAzureMonitorLogs(Batch<LogRecord> batc
 
             logRecord.ForEachScope(s_processScope, properties);
 
-            if (logRecord.EventId.Id != 0)
+            if (!properties.ContainsKey("EventId") && logRecord.EventId.Id != 0)
             {
                 properties.Add("EventId", logRecord.EventId.Id.ToString(CultureInfo.InvariantCulture));
             }
 
-            if (!string.IsNullOrEmpty(logRecord.EventId.Name))
+            if (!properties.ContainsKey("EventName") && !string.IsNullOrEmpty(logRecord.EventId.Name))
             {
                 properties.Add("EventName", logRecord.EventId.Name!.Truncate(SchemaConstants.KVP_MaxValueLength));
             }
diff --git a/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/tests/Azure.Monitor.OpenTelemetry.Exporter.Tests/LogsHelperTests.cs b/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/tests/Azure.Monitor.OpenTelemetry.Exporter.Tests/LogsHelperTests.cs
index 3905ea097d64f..59bbd2b7e0f7d 100644
--- a/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/tests/Azure.Monitor.OpenTelemetry.Exporter.Tests/LogsHelperTests.cs
+++ b/sdk/monitor/Azure.Monitor.OpenTelemetry.Exporter/tests/Azure.Monitor.OpenTelemetry.Exporter.Tests/LogsHelperTests.cs
@@ -183,6 +183,36 @@ public void PropertiesContainEventIdAndEventNameIfSetOnLog()
             Assert.Equal(2, properties.Count);
         }
 
+        [Fact]
+        public void LogRecordAndAttributesContainEventIdAndEventName()
+        {
+            var logRecords = new List<LogRecord>();
+            using var loggerFactory = LoggerFactory.Create(builder =>
+            {
+                builder.AddOpenTelemetry(options =>
+                {
+                    options.AddInMemoryExporter(logRecords);
+                });
+                builder.AddFilter(typeof(LogsHelperTests).FullName, LogLevel.Trace);
+            });
+
+            var logger = loggerFactory.CreateLogger<LogsHelperTests>();
+
+            EventId id = new EventId(1, "TestEvent");
+
+            string log = "Log Information {EventId} {EventName}.";
+            logger.LogInformation(id, log, 100, "TestAttributeEventName");
+
+            var properties = new ChangeTrackingDictionary<string, string>();
+            LogsHelper.GetMessageAndSetProperties(logRecords[0], properties);
+
+            Assert.True(properties.TryGetValue("EventId", out string eventId));
+            Assert.Equal("100", eventId);
+            Assert.True(properties.TryGetValue("EventName", out string eventName));
+            Assert.Equal("TestAttributeEventName", eventName);
+            Assert.Equal(2, properties.Count);
+        }
+
         [Fact]
         public void ValidateSeverityLevels()
         {